Coordination complexes of criiiwith four tridentate schiff base ligands viz. Coordination complexes with metal ions cuii, niii, coii, feiii, mnii, criii, and voii with six ligands formed by condensation products using azides and aldehydes or ketones are characterized. Synthesis, crystal structure and antibacterial activity of a group of mononuclear manganeseii schiff base complexes. Chromiumiii, manganeseii and ironiii complexes based on. All the complexes were characterized on the basis of their micro analytical data, elemental analysis, melting points, ir, uv vis spectra and magnetic moment properties. Synthesis and characterization of chromium iii schiff base. Chromium iii schiff base complexes have been synthesized using schiff base formed by the condensing by the respective aldehyde with diamene in ethanol rectified. A series of novel catalysts were prepared by immobilizing chromiumiii schiff base complexes and acidic ionic liquids onto the surface of mcm41, and characterized by ftir, tg, xrd, sem, tem, nh3tpd, icpoes and n2 sorption studies. Electrochemical behavior, structural, morphological, calf. Synthesis, characterization and antimicrobial activity of. Read syntheses of chromiumiii complexes with schiffbase ligands and their catalytic behaviors for ethylene polymerization, journal of molecular catalysis a.
Tridentate schiff base chromium complexes derived from 1amino2indanol were identified as the optimal catalysts. Molecular and biomolecular spectroscopy on deepdyve, the largest online rental service for scholarly research with thousands of academic publications available at your fingertips. A number of schiffbase complexes have been used as oxygen carriers to mimic complicated biological systems 7, 11. New criii hexacoordinated complexes with tridentate nn. Metal complexes have been prepared by interacting these schiff bases with metal ions viz. Schiff base compounds which contain the azomethine imine group rcn are usually prepared by the condensation of a primary amine with an active carbonyl compound 1 it has been often used as chelating agents ligands in the field of coordination chemistry and schiff base metal complexes were of great interest for many years. From mic values, it was found that cul and voivl were somewhat more potent among other synthesized schiff base metal complexes.
A series of symmetrical tetradentate schiff bases containing the n 2 o 2 donor set and their corresponding chromiumiii complexes have been synthesized and spectrally characterized. Preparation of zinc oxide nanomaterial using unsymmetrical. The salen anion forms complexes with most transition metals. Ru3co12 and rucl3 reacted with the schiff base bis2hydroxyacetophenoneethylenediimine hapenh2 to give ruco2hapenh2 and rucl2hapenh2cl. The obtained complexes showed promising antimicrobial activity when compared to those of parent ligand. Chiral schiff bases according to the general formula. New criii complexes with tridentate base schiff nn. The complexes were synthesized by template method and characterized by elemental analysis chns. The reaction of nitric oxide with some of the chromiumiischiff base complexes gave chromiumiii products of indefinite composition, but three 15nnitrosyls of cobaltiischiff base complexes have been isolated. Chromiumiii complexes of schiff bases sciencedirect. The n1c1c2c3n2cr forms a sixmember ring with the n1crn2 angle 91. Solvent extraction of chromium and copper using schiff base derived from. Files available from the acs website may be downloaded for personal use only.
Abstractthis study describes synthesis, spectroscopic characterization and catalytic activities of feii, ruii, pdii and znii complexes with a novel schiff base ligand l derived from methyl 2amino5,5,7,7tetramethyl4,5,6,7tetrahydrobenzobthiophene3carboxylate and terephthalaldehyde. Solvent extraction of chromium and copper using schiff. The same synthetic procedure gives two series of complexes depending on the amount and rate of addition of potassium carbonate used to deprotonate the schiff base. Electrochemical, spectroelectrochemical and structural characterization of iridium and ruthenium porphyrins, schiffbase biquinone complexes, copper triazole complexes and flavins. Metal schiff base complexes have been well known for their easy synthesis, stability and wide application 1214. Synthesis and characterization of chromiumiii schiff base complexes. Asymmetric reactions catalyzed by chiral tridentate schiff. Solvent extraction of metal chelate complexes has been used as a separation method for a long time. Schif f bases of thiodiazole have good plant growth regulator activity towards auxin and cytokin95. Abstracta tridentate nno donor hydrazine schiff base, hl, was obtained from condensation of pyridine 2carbaldehyde and 4hydroxy. The schiff base and its zinc and antimony complexes are strongly active against leukemic cells cd50 2. Xray crystallographic analysis of a closely related chromium complex reveals a bridged, dimeric structure bearing aquobound six. The work described in this thesis mainly covers the investigations of a series of conjugated schiffbase macrocycles and metal salphen complexes.
Iii complexes of a homologous series of schiffbase ligands. The catalytic activity of the prepared solid catalysts was investigated for the. Eight chromium ii complexes of type, crlh2oxxh2o where l schiff base ligand have been synthesized and characterized on the basis of elemental analysis ir. The preparation, electronic and infrared spectra, and magnetic moments of numerous solid complexes of chromiumiii of the type crsbl2xnh2o l nh 3 or. Equatorially coordinated macrocyclic and schiff base ligands influence the reorganizational barriers for the conversion of criiicrivcrvcrvi. Read structure, photochemistry and magnetic properties of tetrahydrogenated schiff base chromiumiii complexes, spectrochimica acta part a. Thanks to their lewis acidic character, znl complexes show interesting. Both the ligands and the complexes synthesized are characterized by c, h, n, cl and metal analyses, ir, uvvis, tga, and magnetic susceptibility for tentative structure. A schiff base ligand sbl, n2, n3bis anthracen9ylmethylene pyridine2, 3diamine, was synthesized through the condensation of 2,6diaminopyridine and anthracene9carbaldehyde using a 1.
Mixedligand copperii complexes with diethylenetriamine and histidine or methioninehydroxamic acids in water solution. In the present study new schiff base of en4thiophen2 ylmethyleneamino phenylsulfonyl acetamide metal complexes were synthesized and then characterized by various physicochemical and spectral analytical techniques. The kinetics of the aqua ligand substitution in the complexes crschiffbasehzo by thiocyanate have been. Complexes of ironiii and chromium iii salen and salophen schiff bases with bridging 1,3,5. Elemental, spectroscopic and magnetic studies of the reported complexes revealed the proposed structures.
The magnetic moment values of the complexes exhibited the existence of paramagnetic phenomena for a chromium iii complex and diamagnetic phenomena for the other rest complexes. The thermal properties of the complexes were investigated by thermogravimetric techniques. A large number of schiff base n2o2 complexes have been reported so far, and their catalytic and biological properties have been studied intensively 1521. Preparation of zinc oxide nanomaterial using unsymmetrical schiff base complexes maldhure ak 1 and aswar as 2. Thermal behavior of tetradentate schiff base chromiumiii. Insertion of a symmetric metal complex, cr iii 5,5.
Enantioselective ring opening of meso aziridines catalyzed. Lin lili liu xiaohua feng xiiaoming college of chemistry, sichuan university, chengdu 610064, china. Characterization of complexes synthesized using schiff. Criii schiff base complexes obtained from thiourea. Schiff bases have been synthesized by condensing nicotinamide with methyl isobutyl ketone mkn and 2hydroxy acetophenone han. Bydirect interaction of the schiff base with the metal salts the schiff base can be synthesized without using the metal ion and then followed by addition of the metal ion as salt solution for complex formation. These complexes are usually prepared by the reaction of h 2 salen proligand with metal precursors containing builtin bases, such as alkoxides, metal amides, or metal acetate. Approaches to the aqueous chemistry of chromium iv and. This method leads directly to enantioenriched hydroxy silyl enol ether derivatives, which are known to be useful intermediates for the stereocontrolled synthesis of substituted polyol frameworks. Synthesis and characterization of some chromiumiii complexes of. Eight chromiumiii complexes of tetradentate schiff bases have been prepared in situ by condensing of a substituted salicylaldehyde compound with ethylenediamine. These complexes with a cocatalyst are active catalysts in the coupling of co 2 epoxides up to 900 g of polycarbonateg cr was obtained from cyclohexene oxideco 2 a conversion up to 97% in cyclic carbonate was obtained from styrene oxideco 2.
Preparation of artificial metalloenzymes by insertion of chromium iii schiff base complexes into apomyoglobin mutants. Preparation, characterization and antimicrobial activity. Conjugated schiffbase macrocycles and their metal complexes. Microwave synthesis and antimicrobial activity of some copper ii, cobalt ii, nickel ii and chromium iii complexes with schiff base 2, 6pyridinedi carboxaldehydethiosemicarbazone. Mniii ion in the highspin state with s 2 3d 4 is described by 5 d ground term.
Preparation and spectroscopic studies of feii, ruii. Pdf schiff base metal complexes of chromiumiii, manganeseiii. These compounds have been synthesized by conventional as well as microwave methods and characterized by. Complexes of chromiumii with some betadiketones, 2. Results and discussion previously we observed that the aerial oxidation of chromium ii salts in presence of dibasic quadriden tate schiff bases of salicylaldehyde or substituted sali cylaldehyde in suitable solvents is a good method for the synthesis of schiff base complexes of chromium iii.
During the original schiff base complexes crsalprcl 2cl the schiff base also tend to adopt a approximate squareplanar geometry. Iii complexes of a homologous series of schiffbase. This study focuses on the synthesis of coii and criii schiff base complexes obtained from thiourea. Syntheses of chromiumiii complexes with schiffbase. These complexes have been characterized by elemental analysis, ir and electronic spectra, magnetic moments, xrd and thermal analysis. Compared with a square planar structure for individual crystalline schiff base complexes, complexes immobilized on a silica surface suffer a tetrahedral distortion due to the anchoring of a ligand foot to the nanoparticle surface, and that can be one of the causes of a raise in their reaction activity. A catalytic method for the enantioselective ring opening of meso aziridines by tmsn3 is described.
Synthesis and characterization of some mixed schiff base complexes of copper and nickel. The stabilization of chromiumiv and chromiumv in aqueous systems has now been made through designed alterations in franckcondon barriers for the interconversion of various oxidation states of chromium. Systhesis and characterization of some chromium iii schiff base. This can be easily described by the following example.
Synthesis, characterization, and spectroscopic studies of. A series of chromiumiii schiff base complexes immobilized on mcm41 were prepared and characterized by various physicochemical and spectroscopic methods. The metal percentages of newly synthesized schiff base metal complexes which are shown in table 3, give a good agreement with the proposed formula calculated, and confirm binding of the metal ion to ligand sites. Asymmetric reactions catalyzed by chiral tridentate schiff basemetal complexes. Chromium iii schiff base complexes have been synthesized using schiff base formed by the condensing by the. The macrocycles with long alkoxy substituents have the. Chemical on deepdyve, the largest online rental service for scholarly research with thousands of academic publications available at your fingertips.
Synthesis, characterization and biological activity of. The complexes were used for the selective oxidation of alcohols by 30% hydrogen peroxide without any organic solvent, phase transfer catalyst or additive. Complexes based on schiffbase ligands play important roles in biomedical 8, 9, biomimetic, and catalytic systems 10, 11 and in supporting liquid crystalline phases. Unsymmetrical tetradentate schiff base derived from salicylaldehyde, 2hydroxy3methoxy benzaldehyde and ethylenediamine and its complexes with voiv, criii, mniii, feiii and uo2vi have been prepared. Asymmetric catalysis of heteroene reactions with tridentate schiff. The proligand may also be treated with a metal halide, with or without an added base lastly, the proligand may. Synthesis and characterization of a novel schiff base. However, because of the further oxidation products, the selectivities cannot be exceeded 5060% fig.
Structure, photochemistry and magnetic properties of. The preparation, electronic and infrared spectra, and magnetic moments of numerous solid complexes of chromiumiii of the type crsbl2xnh2o l nh3 or. In vitro cytotoxicity activity of novel schiff base ligand. A concerted ene reaction between silyl enol ethers and simple aldehydes is catalyzed by chiral schiff base cr iii complexes with high stereoselectivity see scheme. It has been shown that a very low field 15n nmr signal clearly indicates the presence of a bent mno group. Microwave synthesis and antimicrobial activity of some. C nmr spectra of schiff base ligand and metal complexes are summarised in table 3 and given in fig. Preparation of artificial metalloenzymes by insertion of. Synthesis of coii and criii salicylidenic schiff base complexes. Synthesis, spectral, thermal and biological studies. Ruiii, criii, feiii complexes of schiff base ligands bearing. We used spectroscopic techniques including ir, uvvis.
Tridentate schiff base chromiumiii complex 1 catalyzes the asymmetric heteroene reaction between aryl aldehydes and either 2methoxypropene or 2trimethylsilyloxypropene to provide a series of. Tridentate schiff base chromiumiii complex 1 catalyzes the. The coordination behavior of the metal ions towards to the investigated schiff base takes place through cn and oh groups. Xray crystallographic analysis of a closely related chromium complex reveals a bridged, dimeric. The h 1nmr of metal complexes compared with schiff base ligand infers that there is no appreciable change in the signals of the complex as no hydrogen involves in chelation process. Schiff base and its complexes show that the metals exhibited higher antimicrobial activity than the schiff base on comparison. Thermal behavior of tetradentate schiff base chromiumiii complexes article pdf available in journal of thermal analysis and calorimetry 1152. Complexes of general formulation crschiffbaseh2o2x, where schiffbase1, 2bissalicylideneaminoethane. Jahnteller jt distortion lowers the symmetry up to d 4h tetragonal geometry, which leads to an additional splitting of 5 e g into 5 b 1g and 5 a 1g and of 5 t 2g into 5 e g and 5 b 2g. Preparation and spectroscopic investigation of a schiff. Tridentate schiff base chromium iii complex 1 catalyzes the asymmetric heteroene reaction between aryl aldehydes and either 2methoxypropene or 2trimethylsilyloxypropene to provide a series of.
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